A modified UNIQUAC equation for mixtures containing self-associating compounds
نویسندگان
چکیده
منابع مشابه
A Modified van der Waals Mixture Theory for Associating Fluids: Application to Ternary Aqueous Mixtures
In this study a simple and general chemical association theory is introduced. The concept of infinite equilibrium model is re-examined and true mole fractions of associated species are calculated. The theory is applied to derive the distribution function of associated species. As a severe test the application of presented theory to the van der Waals mixture model is introduced in order to p...
متن کاملA modified extended UNIQUAC model for proteins
A modification of the extended UNIQUAC model is proposed for the description of the non-ideality of protein solutions. Here, the Staverman–Guggenheim combinatorial contribution used in extended UNIQUAC model is replaced by the Flory–Huggins term to take into account the size differences between the protein and solvent. This new model allows an excellent description of the activity coefficients ...
متن کاملa modified van der waals mixture theory for associating fluids: application to ternary aqueous mixtures
in this study a simple and general chemical association theory is introduced. the concept of infinite equilibrium model is re-examined and true mole fractions of associated species are calculated. the theory is applied to derive the distribution function of associated species. as a severe test the application of presented theory to the van der waals mixture model is introduced in order to perfo...
متن کاملThe Modified Enskog Equation for Mixtures
synopsis In a previous paper it was shown that a modified form of the Enskog equation, applied to mixtures of hard spheres, should be considered as the correct extension of the usual Enskog equation to the case of mixtures. The main argument was that the modified Enskog equation leads to linear transport coefficients which are in complete agreement with the laws of irreversible thermodynamics. ...
متن کاملSelf-Assembly in Mixtures of Polymers and Small Associating Molecules
The interaction between a flexible polymer in a good solvent and smaller associating solute molecules such as amphiphiles (surfactants) is considered theoretically. Attractive correlations, induced in the polymer because of the interaction, compete with intra-chain repulsion and eventually drive a joint self-assembly of the two species, accompanied by partial collapse of the chain. Results of t...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Brazilian Journal of Chemical Engineering
سال: 2005
ISSN: 0104-6632
DOI: 10.1590/s0104-66322005000300015